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dc.contributor.authorSchipper, Desmond E.
Chen, Jing-Han
Whitmire, Kenton H.
dc.date.accessioned 2017-11-14T18:08:22Z
dc.date.available 2017-11-14T18:08:22Z
dc.date.issued 2017
dc.identifier.citation Schipper, Desmond E., Chen, Jing-Han and Whitmire, Kenton H.. "Iron carbonyl clusters with ECl2 units (E = P, As)." Journal of Organometallic Chemistry, 849-850, (2017) Elsevier: 279-285. https://doi.org/10.1016/j.jorganchem.2017.03.008.
dc.identifier.urihttps://hdl.handle.net/1911/98797
dc.description.abstract Reaction of [PPN][HFe(CO)4] (PPN = bis(triphenylphosphine)iminium) with PCl3 in a 1:1 ratio produced small amounts of [PPN][P{Fe(CO)4}2Cl2] ([PPN][Ia]). Reaction of [Et4N][HFe(CO)4] with AsCl3 in a 1:0.75 ratio in THF at −78 °C produced [Et4N][As{Fe(CO)4}2Cl2] ([PPN][Ib]) as the majority product. The compound [PPN][(CO)4FePCl2O] ([PPN][II]) was obtained from the reaction of Fe2(CO)9 with PCl3 in THF. In contrast, [Et4N][HFe(CO)4] reacted with PCl3 at −78 °C in a 2:1 ratio to yield [Et4N][Fe2(CO)6{(μ4-PFe(CO)4)2(μ-CO)}{μ-PCl2}] ([Et4N][III]) as the majority product. The compounds were characterized spectroscopically and by single-crystal X-ray diffraction analyses.
dc.language.iso eng
dc.publisher Elsevier
dc.rights This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Elsevier.
dc.title Iron carbonyl clusters with ECl2 units (E = P, As)
dc.type Journal article
dc.citation.journalTitle Journal of Organometallic Chemistry
dc.subject.keywordPhosphorus
Arsenic
Iron
Metal carbonyl
Pnictide
Pnictogen
Carbonyl cluster
Chlorophosphine
Phosphorus trichloride
dc.citation.volumeNumber 849-850
dc.identifier.digital ECl2Manuscript2017.02.23_DES
dc.type.dcmi Text
dc.identifier.doihttps://doi.org/10.1016/j.jorganchem.2017.03.008
dc.type.publication post-print
dc.citation.firstpage 279
dc.citation.lastpage 285


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