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dc.contributor.authorKornyshev, Alexei A.
Twidale, Rebecca M.
Kolomeisky, Anatoly B.
dc.date.accessioned 2017-08-02T14:52:15Z
dc.date.available 2017-08-02T14:52:15Z
dc.date.issued 2017
dc.identifier.citation Kornyshev, Alexei A., Twidale, Rebecca M. and Kolomeisky, Anatoly B.. "Current-Generating Double-Layer Shoe with a Porous Sole: Ion Transport Matters." The Journal of Physical Chemistry C, 121, no. 14 (2017) American Chemical Society: 7584-7595. https://doi.org/10.1021/acs.jpcc.6b11385.
dc.identifier.urihttps://hdl.handle.net/1911/96166
dc.description.abstract Generating electrical current from mechanically forced variation of the contact area of electrode/electrolyte interface underpins one of the scenarios of harvesting electrical current from walking. We develop here theory of an electrical shoe with a porous sole with an account of both convection of the liquid electrolyte under pressure and ion migration with transmission-line-type charging of electrical double layer at the pore walls. We show here that ion transport limitations can dramatically reduce the generated current and power density. The developed theory describes the time dependence of the generated current and reveals its dependence on the main operation parameters, the amplitudes of oscillating pressure and frequency, in relation to the system parameters.
dc.language.iso eng
dc.publisher American Chemical Society
dc.rights This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.
dc.title Current-Generating Double-Layer Shoe with a Porous Sole: Ion Transport Matters
dc.type Journal article
dc.citation.journalTitle The Journal of Physical Chemistry C
dc.contributor.org Center for Theoretical Biological Physics
dc.citation.volumeNumber 121
dc.citation.issueNumber 14
dc.identifier.digital TL-shoe-final
dc.type.dcmi Text
dc.identifier.doihttps://doi.org/10.1021/acs.jpcc.6b11385
dc.type.publication post-print
dc.citation.firstpage 7584
dc.citation.lastpage 7595


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