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dc.contributor.authorSchmidt, Joel E.
Fu, Donglong
Deem, Michael W.
Weckhuysen, Bert M.
dc.date.accessioned 2017-01-27T22:23:42Z
dc.date.available 2017-01-27T22:23:42Z
dc.date.issued 2016
dc.identifier.citation Schmidt, Joel E., Fu, Donglong, Deem, Michael W., et al.. "Template–Framework Interactions in Tetraethylammonium-Directed Zeolite Synthesis." Angewandte Chemie, 55, no. 52 (2016) Wiley: 16044-16048. http://dx.doi.org/10.1002/anie.201609053.
dc.identifier.urihttps://hdl.handle.net/1911/93792
dc.description.abstract Zeolites, having widespread applications in chemical industries, are often synthesized using organic templates. These can be cost-prohibitive, motivating investigations into their role in promoting crystallization. Herein, the relationship between framework structure, chemical composition, synthesis conditions and the conformation of the occluded, economical template tetraethylammonium (TEA+) has been systematically examined by experimental and computational means. The results show two distinct regimes of occluded conformer tendencies: 1) In frameworks with a large stabilization energy difference, only a single conformer was found (BEA, LTA and MFI). 2) In the frameworks with small stabilization energy differences (AEI, AFI, CHA and MOR), less than the interconversion of TEA+ in solution, a heteroatom-dependent (Al, B, Co, Mn, Ti, Zn) distribution of conformers was observed. These findings demonstrate that host–guest chemistry principles, including electrostatic interactions and coordination chemistry, are as important as ideal pore-filling.
dc.language.iso eng
dc.publisher Wiley
dc.rights This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited, and is not used for commercial purposes.
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.title Template–Framework Interactions in Tetraethylammonium-Directed Zeolite Synthesis
dc.type Journal article
dc.citation.journalTitle Angewandte Chemie
dc.citation.volumeNumber 55
dc.citation.issueNumber 52
dc.type.dcmi Text
dc.identifier.doihttp://dx.doi.org/10.1002/anie.201609053
dc.identifier.pmcid PMC5215409
dc.identifier.pmid 27874242
dc.type.publication publisher version
dc.citation.firstpage 16044
dc.citation.lastpage 16048


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This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited, and is not used for commercial purposes.
Except where otherwise noted, this item's license is described as This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited, and is not used for commercial purposes.