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dc.contributor.authorZhou, Zhe
Ma, Zhiwei
Behnke, Nicole Erin
Gao, Hongyin
Kürti, László
dc.date.accessioned 2017-01-27T19:05:16Z
dc.date.available 2017-01-27T19:05:16Z
dc.date.issued 2017
dc.identifier.citation Zhou, Zhe, Ma, Zhiwei, Behnke, Nicole Erin, et al.. "Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals." Journal of the American Chemical Society, 139, no. 1 (2017) American Chemical Society: 115-118. http://dx.doi.org/10.1021/jacs.6b12712.
dc.identifier.urihttps://hdl.handle.net/1911/93785
dc.description.abstract Herein we disclose a novel method for the facile transfer of primary (−NH2) and secondary amino groups (−NHR) to heteroaryl- as well as arylcuprates at low temperature without the need for precious metal catalysts, ligands, excess reagents, protecting and/or directing groups. This one-pot transformation allows unprecedented functional group tolerance and it is well-suited for the amination of electron-rich, electron-deficient as well as structurally complex (hetero)arylmetals. In some of the cases, only catalytic amounts of a copper(I) salt is required.
dc.language.iso eng
dc.publisher American Chemical Society
dc.rights This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.
dc.title Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals
dc.type Journal article
dc.citation.journalTitle Journal of the American Chemical Society
dc.contributor.org BioScience Research Collaborative
dc.citation.volumeNumber 139
dc.citation.issueNumber 1
dc.type.dcmi Text
dc.identifier.doihttp://dx.doi.org/10.1021/jacs.6b12712
dc.identifier.pmid 28004917
dc.type.publication post-print
dc.citation.firstpage 115
dc.citation.lastpage 118


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