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    Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals

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    Author
    Zhou, Zhe
    Ma, Zhiwei
    Behnke, Nicole Erin
    Gao, Hongyin
    Kürti, László
    Date
    2017
    Citation
    Zhou, Zhe, Ma, Zhiwei, Behnke, Nicole Erin, et al.. "Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals." Journal of the American Chemical Society, 139, no. 1 (2017) 115-118. http://dx.doi.org/10.1021/jacs.6b12712.
    Published Version
    http://dx.doi.org/10.1021/jacs.6b12712
    Abstract
    Herein we disclose a novel method for the facile transfer of primary (−NH2) and secondary amino groups (−NHR) to heteroaryl- as well as arylcuprates at low temperature without the need for precious metal catalysts, ligands, excess reagents, protecting and/or directing groups. This one-pot transformation allows unprecedented functional group tolerance and it is well-suited for the amination of electron-rich, electron-deficient as well as structurally complex (hetero)arylmetals. In some of the cases, only catalytic amounts of a copper(I) salt is required.
    Type
    Journal article
    Citable link to this page
    http://hdl.handle.net/1911/93785
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    • Chemistry Publications [403]
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    Managed by the Digital Scholarship Services at Fondren Library, Rice University
    Physical Address: 6100 Main Street, Houston, Texas 77005
    Mailing Address: MS-44, P.O.BOX 1892, Houston, Texas 77251-1892