Photoinduced force mapping of plasmonic nanostructures
Tumkur, Thejaswi U.
Halas, Naomi J.
The ability to image the optical near-fields of nanoscale structures, map their morphology and concurrently obtain spectroscopic information, all with high spatiotemporal resolution, is a highly sought-after technique in nanophotonics. As a step towards this goal, we demonstrate the mapping of electromagnetic forces between a nanoscale tip and an optically excited sample consisting of plasmonic nanostructures, with an imaging platform based on atomic force microscopy. We present the first detailed joint experimental-theoretical study of this type of photo-induced force microscopy. We show that the enhancement of near-field optical forces in gold disk dimers and nanorods follows the expected plasmonic field enhancements, with strong polarization sensitivity. We then introduce a new way to evaluate optically-induced tip-sample forces by simulating realistic geometries of the tip and sample. We decompose the calculated forces into in-plane and out-of-plane components and compare the calculated and measured force enhancements in the fabricated plasmonic structures. Finally, we show the usefulness of photo-induced force mapping for characterizing the heterogeneity of near-field enhancements in precisely e-beam fabricated nominally alike nanostructures - a capability of widespread interest for precise nanomanufacturing, SERS and photocatalysis applications.
NEWS COVERAGE: A news release based on this journal publication is available online: http://news.rice.edu/2016/12/14/light-provides-pull-for-future-nanocatalyst-measurement/
plasmonics; near-field scanning optical microscopy; gradient force; photocatalysis; nanocharacterization
Citable link to this pagehttps://hdl.handle.net/1911/92710
RightsThis is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.
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