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dc.contributor.authorSchipper, Desmond E.
Ikhlef, Djamila
Khalal, Samila
Saillard, Jean-Yves
Whitmire, Kenton H.
dc.date.accessioned 2016-09-19T21:20:39Z
dc.date.available 2016-09-19T21:20:39Z
dc.date.issued 2016
dc.identifier.citation Schipper, Desmond E., Ikhlef, Djamila, Khalal, Samila, et al.. "New Main-Group-Element-Rich nido-Octahedral Cluster System: Synthesis and Characterization of [Et4N][Fe2(CO)6(μ3-As){μ3-EFe(CO)4}2]." Inorganic Chemistry, 55, no. 13 (2016) American Chemical Society: 6679-6684. http://dx.doi.org/10.1021/acs.inorgchem.6b00921.
dc.identifier.urihttps://hdl.handle.net/1911/91579
dc.description.abstract A series of clusters of the form [Et4N][Fe2(CO)6(μ3-As)}(μ3-EFe(CO)4)], where E is either P or As, were synthesized from [Et4N]2[HAs{Fe(CO)4}3] and ECl3. AsCl3 gives the As-only compound; PCl3 produces compounds having two As atoms with one P atom, or one As atom and two P atoms, and they can exist as two possible isomers, one of which is chiral. The As2P and AsP2clusters cocrystallize, and their structure as determined by single-crystal X-ray diffraction is given along with the structure of the As-only cluster. Analytical data as well as density functional theory calculations support the formation and geometries of the new molecules.
dc.language.iso eng
dc.publisher American Chemical Society
dc.rights This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the American Chemical Society.
dc.title New Main-Group-Element-Rich nido-Octahedral Cluster System: Synthesis and Characterization of [Et4N][Fe2(CO)6(μ3-As){μ3-EFe(CO)4}2]
dc.type Journal article
dc.citation.journalTitle Inorganic Chemistry
dc.citation.volumeNumber 55
dc.citation.issueNumber 13
dc.type.dcmi Text
dc.identifier.doihttp://dx.doi.org/10.1021/acs.inorgchem.6b00921
dc.type.publication post-print
dc.citation.firstpage 6679
dc.citation.lastpage 6684


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