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    Molecular structure effects on the theory of corresponding states

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    Author
    Gilbert, Lawrence Lamar
    Date
    1963
    Advisor
    Leland, Thomas W.
    Degree
    Master of Science
    Abstract
    A method is proposed to take into account deviations from the principle of corresponding states due to shape and size effects. Factors for use with the critical constants as reducing parameters are determined for the n-paraffin hydrocarbon series, methane through normal octane for the gas phase from second virial coefficient data. The prediction of pure component thermodynamic properties is evaluated. Applications to a vapor-liquid equilibrium calculation procedure based on composition dependent pseudo-criticals and the corresponding states theory are discussed.
    Citation
    Gilbert, Lawrence Lamar. "Molecular structure effects on the theory of corresponding states." (1963) Master’s Thesis, Rice University. https://hdl.handle.net/1911/89681.
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    • Rice University Electronic Theses and Dissertations [13409]

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    Home | FAQ | Contact Us | Privacy Notice | Accessibility Statement
    Managed by the Digital Scholarship Services at Fondren Library, Rice University
    Physical Address: 6100 Main Street, Houston, Texas 77005
    Mailing Address: MS-44, P.O.BOX 1892, Houston, Texas 77251-1892
    Site Map