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Derivation of an infinite-dilution activity coefficient model and application to two-component vapor-liquid equilibria data
(1988)
Infinite-dilution fugacity coefficients were obtained for the binary system fluorene/phenanthrene at thirteen temperatures by fitting total pressure across the entire mole fraction range by a computer routine. A thermodynamically ...
Viscosity and spin-lattice relaxation time of supercritical carbon dioxide-n-hexadecane mixtures, and molar density and isobaric heat capacity ratios for dense fluids
(1995)
In part one, correlations between viscosity and proton spin-lattice relaxation time are developed for CO$\sb2$ - n-Hexadecane mixtures in equilibrium with their vapor-phase in the vicinity of critical points. A microscopic ...
Thermodynamics and kinetics studies of formation and decomposition of clathrates hydrates of methane, carbon dioxide and their mixtures using a differential heat flux calorimeter
(1997)
A high pressure heat flux calorimeter in isobaric, temperature-ramping mode has been used to measure the solubility of pure methane, pure carbon dioxide and methane-carbon dioxide mixtures. The solubility measurements ...
Extension of Pitzer corresponding states correlations using new vapor pressure measurements of then-alkanes C(10) to C(28)
(1990)
Pitzer et al. (1955) three-parameter (T$\sb{\rm c}$, P$\sb{\rm c}$,$\omega$) corresponding states principle (CSP) correlations for saturated properties are extended to long-chain n-alkanes and to other classes of compounds ...
Corresponding states correlations relating proton spin-lattice relaxation rates of hydrocarbons to viscosities at advanced pressures
(1994)
A new five-parameter corresponding states model has been developed for viscosity and proton spin-lattice relaxation rate applicable to a variety of hydrocarbons in the dense fluid phase region.
This model is the key to the ...
Isochoric PVT studies of binary fluid mixtures: The hydrogen-methane and methane-methanol systems
(1991)
The isochoric PVT behavior of two binary fluid mixtures has been studied over extensive ranges of temperature and pressure. Emphasis in both experimental investigations was on definition of single-phase compressed liquid ...
High pressure NMR study of carbon dioxide and supercritical carbon dioxide-n-hexadecane mixtures
(1992)
For the first time, an NMR spectrometer equipped with a high pressure probe has been interfaced with a Vapor-Liquid-Equilibrium apparatus to study solvent-solute interactions in supercritical fluids. The following three ...
Elucidation of the formation and decomposition of clathrate hydrates of natural gases through gas solubility measurements
(1996)
Through isobaric temperature ramping experiments, the solubility of pure methane, ethane, propane, carbon dioxide gases and a methane-propane gas mixture in pure liquid water has been measured. The experiments are conducted ...