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Band evolution and shell structure in large clusters: Aluminum(3-60)anion, copper(1-1113)anion, silver(1-58)anion, and gold(1-223)anion
Photoelectron spectroscopy of negatively, charged clusters of aluminum, copper, silver, and gold reveals electronic shell structure and electron energy band development. Photodetachment experiments on Au$\sb6\sp-$ also ...
Electron transfer in K(nd) collisions with attaching molecules at low-to-intermediate n
Negative ion formation via electron transfer in thermal energy collisions between K(nd) Rydberg atoms and simple polyatomic molecules is studied at low-to-intermediate values of principal quantum number, n (n $<$ 40). At ...
Jet-cooled radical spectroscopy using a color center laser
Jet-cooled radical spectroscopy has been developed for its potential application to high resolution infrared spectroscopic studies of large radicals. In general, radicals containing more than three atoms heavier than ...
Application of quantum mechanical methods to chemical reactions
A variety of quantum mechanical methods have been developed and applied to the study of highly energized "pre-reactive" species involved in chemical reactions. We have examined the character of transition states for both ...