Now showing items 1-3 of 3
Kinetics and dynamics of azoalkane photofragmentation: Direct studies using transient CARS spectroscopy
A fundamental and long-standing question surrounds the mechanism of primary bond cleavage in azoalkanes: do the two C-N bonds break in a synchronous or a stepwise manner? When a vapor phase azoalkane absorbs near ultraviolet ...
Studies of the vapor phase photodissociation of azomethane-d(6)
The photodissociation of fully deuterated azomethane into two CD$\sb3$ radicals and N$\sb2$ was studied using transient CARS spectroscopy as a nanosecond resolved probe of the photoproducts. The Raman-active $\nu\sb1$ ...
CARS studies of the quenching of excited sulfur atoms by rare gases: Fine structure selectivity in electronic-to-translational energy transfer
In the first use of the Raman effect to detect sulfur atoms, transient CARS spectroscopy has revealed novel relaxation effects in sulfur formed through multiple photon excitation of carbon disulfide vapor. Ground term ...