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Matrix reactions of uranium fluorides as studied by infrared spectroscopy
The Infrared spectra of UF^4 were recorded In matrices of neon, argon, krypton, xenon, oxygen, nitrogen, nitric oxide, and carbon monoxide* The data from these spectra support a tetrahedral structure for UF^4 in the gas ...
Base catalyzed elimination of methyl enol ethers
The formation of naphthalenes on treatment of enol ethers of tetralones with strong bases proceeded in good yields under moderate conditions. Dienol ethers of octalinones gave tetralins in lower yields and under more ...
Cyclopropanation of dienol ethers
The copper-catalysed, thermal decompositions of ethyl diazoacetate and diazoacetone in the presence of 1-methoxycyclohexa-1,3-diene, l-methoxy-4-methylcyclohexa-l,3-diene, 1-methoxybuta-l,3-diene, 1-ethoxybuta-l,3-diene ...
The photochemistry of (alpha)-acetylenic ketones
An investigation of the photochemistry of several a-acetylenic ketones was instituted. The photochemical behavior of 2-octyne-4-one 22 was compared with that of 2-octene-4-one 2j. Whereas the latter underwent only cis-trans ...