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Carbon-13 nuclear magnetic resonance studies of some organo-rhodium complexes
This study was concerned with the analysis of bonding in rhodium(I) square planar complexes of the type RhCl(CO)L2 where L equals tertiary phosphine, arsine, stibine, and amine. Since Rh(I) complexes have been shown to be ...
Proton resonance detection and identification of intermediates in the pyridoxal catalyzed dehydration of serine and serine-indole synthesis of tryptophan
In an investigation of a proposed mechanism for pyridoxal catalyzed serine dehydration and serine-indole synthesis of tryptophan, pmr spectra of solutions containing 0.05M pyridoxal, serine, tryptophari, and/or indole in ...
The reactions of silicon difluoride with sulfur compounds: the silicon-sulfur bond
The reactions of silicon difluoride with several sulfur containing compounds have been investigated in an attempt to synthesize compounds containing the silicon-sulfur bond. Of the previous reactions of silicon difluoride ...
Part I: The artifically stirred reactor for flow kinetics. Part II: The liquid phase rearrangement of methyl allyl xanthate
An artificially stirred reactor for general use in gas phase kinetics experiments was designed and built. The new reactor shows better performance than an ordinary diffusion stirred reactor, except when the stirrer is ...
Ion-molecule reactions in mixtures of methane and carbon dioxide
Using a quadrupole mass filter, ion-molecule reactions in mixtures of methane and carbon dioxide were investigated at pressures of 0.1-0.4 torn. Rate constants for several of the reactions were determined and it was found ...