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Part I.~Reduction of azoalkanes by benzhydryl radicals. Part II.~Thermolysis and photolysis of an alpha-aminoazoalkane, 2-tert-butylazo-2-dimethylaminopropane. Part III.~A reinvestigation of the photochemistry of trifluoromethylazocyclopropane
Benzhydryl radicals donate a hydrogen atom rapidly to the less hindered nitrogen atom of aliphatic and aromatic azo compounds, leading to the corresponding hydrazines. When the initially formed hydrazyl radical possesses ...
Studies of the vapor phase photodissociation of azomethane-d(6)
The photodissociation of fully deuterated azomethane into two CD$\sb3$ radicals and N$\sb2$ was studied using transient CARS spectroscopy as a nanosecond resolved probe of the photoproducts. The Raman-active $\nu\sb1$ ...