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Matrix reactions of silicon difluoride as studied by infrared spectroscopy
Infrared matrix isolation spectroscopy has been employed to characterize monomeric silicon difluoride. Warm-up experiments show the development of several sets of new bands which indicate that this molecule polymerizes ...
Chemical syntheses in electric discharge
Several types of radio-frequency, induction-coupled plasma torches have been used for studying gaseous and gas-solid reactions at high temperatures. After a detailed examination of the various parameters which affect the ...
Overhauser effect and NMR spectra of n-methyl methylenimine
Pure liquid samples of the simple but rather reactive species N-Methyl Methylenimine were studied at -60°C. The conventional NMR spectra and double resonance spectra were taken. The NMR constants and relative signs of three ...