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Thermodynamics and kinetics studies of formation and decomposition of clathrates hydrates of methane, carbon dioxide and their mixtures using a differential heat flux calorimeter
A high pressure heat flux calorimeter in isobaric, temperature-ramping mode has been used to measure the solubility of pure methane, pure carbon dioxide and methane-carbon dioxide mixtures. The solubility measurements ...
Viscosity and spin-lattice relaxation time of supercritical carbon dioxide-n-hexadecane mixtures, and molar density and isobaric heat capacity ratios for dense fluids
In part one, correlations between viscosity and proton spin-lattice relaxation time are developed for CO$\sb2$ - n-Hexadecane mixtures in equilibrium with their vapor-phase in the vicinity of critical points. A microscopic ...
Elucidation of the formation and decomposition of clathrate hydrates of natural gases through gas solubility measurements
Through isobaric temperature ramping experiments, the solubility of pure methane, ethane, propane, carbon dioxide gases and a methane-propane gas mixture in pure liquid water has been measured. The experiments are conducted ...
Corresponding states correlations relating proton spin-lattice relaxation rates of hydrocarbons to viscosities at advanced pressures
A new five-parameter corresponding states model has been developed for viscosity and proton spin-lattice relaxation rate applicable to a variety of hydrocarbons in the dense fluid phase region. This model is the key to the ...