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Part I.~Reduction of azoalkanes by benzhydryl radicals. Part II.~Thermolysis and photolysis of an alpha-aminoazoalkane, 2-tert-butylazo-2-dimethylaminopropane. Part III.~A reinvestigation of the photochemistry of trifluoromethylazocyclopropane
Benzhydryl radicals donate a hydrogen atom rapidly to the less hindered nitrogen atom of aliphatic and aromatic azo compounds, leading to the corresponding hydrazines. When the initially formed hydrazyl radical possesses ...
Ultraviolet photoelectron spectroscopy of clusters with a magnetic time of flight photoelectron spectrometer
The nature of metal and semi-conductor bonding has been investigated via UV photoelectron spectroscopy of cluster anions. Electrons from negative cluster ions of the desired mass are photodetached and then collected with ...