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Part I.~Reduction of azoalkanes by benzhydryl radicals. Part II.~Thermolysis and photolysis of an alpha-aminoazoalkane, 2-tert-butylazo-2-dimethylaminopropane. Part III.~A reinvestigation of the photochemistry of trifluoromethylazocyclopropane
Benzhydryl radicals donate a hydrogen atom rapidly to the less hindered nitrogen atom of aliphatic and aromatic azo compounds, leading to the corresponding hydrazines. When the initially formed hydrazyl radical possesses ...
THE SYNTHESIS OF CATIONIC BIS(ETA(6)-ARENE)MANGANESE SANDWICH COMPLEXES
The use of elemental iodine as an in situ oxidant allows the metal vapor synthesis of bis($\eta\sp 6$-arene)manganese cationic sandwich complexes from alkyl substituted arenes. These stable 18 electron species are isolated ...
PART I. INTRAMOLECULAR ENERGY TRANSFER ACROSS AN ESTER BRIDGE: A STUDY OF THE SPHERE OF QUENCHING MODEL. PART II. THE STEREOCHEMISTRY OF 4-BENZOYL-2,3-DIAZABICYCLO (2.2.2) OCT-2-ENE
Part I. A series of bichromophoric molecules linked by an ester bridge is synthesized, and their photochemical and intramolecular energy transfer properties are examined. If benzophenone and naphthalene are held approximately ...
Synthetic studies towards the total synthesis of renieramycin A (Antibiotics)
Formation of the skeleton of renieramycin A was achieved through sequential condensations of piperazinedione and substituted benzaldehydes. One of the key reactions of this synthesis, oxidation of benzylic position, produced ...