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Thermal and photochemical decomposition of azo and azoxyalkanes
The photolysis of vicinal azoazoxy compound 20 gave azo-side extrusion of N$\sb2$ and formation of azoxy products resulting from radical disproportionation and recombination. Photolysis of vicinal bisazoxy compound 21 ...
Generation of radical anions by decomposition of azo compounds
A new method for the generation of radical anions has been developed. Homolytic cleavage of an azo compound bearing a negative charge $\beta$ to the N=N linkage creates a radical anion intermediate. The radical anions so ...
Conversion of methoxy vinyl ethers into glyoxal ketals
A technique for the elaboration of ene products derived from aldehydes and 2-methoxypropene into glyoxal monoketals 5 has been devised, and some reactions of the resulting aldehydes have been examined. This methodology ...