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Preliminary studies in the total synthesis of verrucarol
A preliminary investigation was undertaken to find a route to the cis A-B ring fusion of the sesquiterpene alcohol verrucarol. To synthesize the desired cis-lactone (47), methylacetoacetate (60) was alkylated with ...
The photochemistry of 2,4- and 2,6-cyclo-octadienone
Medium-ring unsaturated ketones have been found to undergo several types of photochemical reactions, including cis-trans isomerization of double bonds, rearrangements, and bridging to bicyclic products. In several instances ...
Synthetic routes to atisine