Now showing items 171-175 of 175
Spectrophotometric analysis for carbanions as a method of studying proton transfer rates
The direct spectrophotometric analysis for carbanions was considered as a method for measuring the kinetics of proton transfer reactions. It was applied to the reaction of 2-nitropropane with piperidine in water and 50% ...
Part I: The artifically stirred reactor for flow kinetics. Part II: The liquid phase rearrangement of methyl allyl xanthate
An artificially stirred reactor for general use in gas phase kinetics experiments was designed and built. The new reactor shows better performance than an ordinary diffusion stirred reactor, except when the stirrer is ...
Ion-molecule reactions in mixtures of methane and carbon dioxide
Using a quadrupole mass filter, ion-molecule reactions in mixtures of methane and carbon dioxide were investigated at pressures of 0.1-0.4 torn. Rate constants for several of the reactions were determined and it was found ...