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Progress towards a model compound for the active site of sulfite reductase. Part I. Synthesis of tetrathiol porphyrin ligands. Part II. Reaction of a tetrathiol porphyrin with the iron-sulfur cubane cluster
Part I. Novel mercaptoethoxy and mercaptoxylyleneoxy derivatives of meso-tetraphenylporphyrin, H$\sb2$TPP, and meso-tetranaphthalporphyrin, H$\sb2$TNP, with the potential for coordinating an iron-sulfur cubane cluster, ...