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    Structural chemistry of fluoride and oxofluoride complexes of titanium(IV)

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    Author
    Davidovich, Ruven L.
    Marinin, Dmitry V.
    Stavila, Vitalie
    Whitmire, Kenton H.
    Date
    2015
    Citation
    Davidovich, Ruven L., Marinin, Dmitry V., Stavila, Vitalie, et al.. "Structural chemistry of fluoride and oxofluoride complexes of titanium(IV)." Coordination Chemistry Reviews, 299, (2015) 61-82. http://dx.doi.org/10.1016/j.ccr.2015.04.002.
    Published Version
    http://dx.doi.org/10.1016/j.ccr.2015.04.002
    Abstract
    The crystal structures of 119 fluoride and oxofluoride complexes of titanium(IV) (88 fluoride and 31 oxofluoride compounds) published to date have been analyzed and reviewed. Depending on the degree and nature of the association of structural units, the analyzed structures can be divided into monomeric, dimeric, oligomeric, and polymeric, including chain and layered polymeric structures. The manuscript describes the occurrence of various structural motifs, the coordination and geometry of complex anions and cations, as well as the driving forces behind supramolecular crystal assembly. A comprehensive table is compiled to provide details about composition, values of terminal and bridging TiF and TiO bonds, as well as the corresponding references. A table of crystallographic data for the investigated fluoride and oxofluoride complexes of titanium(IV) is presented in the Appendix.
    Keyword
    titanium(IV); fluoride; oxofluoride; complex; crystal structure; More... monomeric; oligomeric; polymeric Less...
    Type
    Journal article
    Citable link to this page
    http://hdl.handle.net/1911/80755
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    • Chemistry Publications [403]
    • Faculty Publications [2827]

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    Managed by the Digital Scholarship Services at Fondren Library, Rice University
    Physical Address: 6100 Main Street, Houston, Texas 77005
    Mailing Address: MS-44, P.O.BOX 1892, Houston, Texas 77251-1892