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dc.contributor.authorKumar, Ish
Andrews, Phil
Whitmire, Kenton H.
dc.date.accessioned 2015-02-11T15:45:10Z
dc.date.available 2015-02-11T15:45:10Z
dc.date.issued 2015
dc.identifier.citation Kumar, Ish, Andrews, Phil and Whitmire, Kenton H.. "The Unexpected Isolation of Bismuth Tris(carboxylate) Hydrates: Syntheses and Structures of [Bi(Hsal)3(H2O)] and [Bi(Hanth)3(H2O)] (H2sal = 2-OH-C6H4CO2H, Hanth = 2-NH2-C6H4CO2H)." European Journal of Inorganic Chemistry, 2015, no. 4 (2015) Wiley: 605-608. http://dx.doi.org/10.1002/ejic.201403019.
dc.identifier.urihttps://hdl.handle.net/1911/79027
dc.description.abstract A complex of the composition [Bi(2-OH-C6H4CO2)3(H2O)] (1) was isolated from the 1:3 reaction of BiPh3 with H2sal (H2sal = salicylic acid = 2-OH-C6H4CO2H) in wet xylene, and the analogous anthranilate compound [Bi(2-NH2-C6H4CO2)3(H2O)] (2) was obtained from the 1:3 reaction of Bi(OtBu)3 with Hanth (Hanth = anthranilic acid = 2-NH2-C6H4CO2H) in tetrahydrofuran. Compounds 1 and 2 were fully characterized spectroscopically and by single-crystal X-ray diffraction. Compounds 1 and 2 crystallize in the triclinic space group and display the η2-(O,O′) binding mode for the oxygen atoms of the carboxylate ligands. There are two independent molecules in the asymmetric units of 1 and 2 that are connected by a weak bridging interaction of the OH or NH2 group to an adjacent molecule. Both bismuth atoms are bound to a H2O molecule, but the distances are highly asymmetric, long Bi···O lengths ranging from 2.74 to 2.89 Å.
dc.language.iso eng
dc.publisher Wiley
dc.rights This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by Wiley.
dc.title The Unexpected Isolation of Bismuth Tris(carboxylate) Hydrates: Syntheses and Structures of [Bi(Hsal)3(H2O)] and [Bi(Hanth)3(H2O)] (H2sal = 2-OH-C6H4CO2H, Hanth = 2-NH2-C6H4CO2H)
dc.type Journal article
dc.contributor.funder Welch Foundation
dc.citation.journalTitle European Journal of Inorganic Chemistry
dc.subject.keywordbismuth
salicylates
carb-oxylates
hydrates
hydrolysis
dc.citation.volumeNumber 2015
dc.citation.issueNumber 4
dc.type.dcmi Text
dc.identifier.doihttp://dx.doi.org/10.1002/ejic.201403019
dc.identifier.grantID C-0976 (Welch Foundation)
dc.type.publication post-print
dc.citation.firstpage 605
dc.citation.lastpage 608


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