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dc.contributor.authorBoyd , Tyler D.
Kumar, Ish
Wagner, Eric E.
Whitmire, Kenton H.
dc.date.accessioned 2014-07-30T16:23:09Z
dc.date.available 2014-07-30T16:23:09Z
dc.date.issued 2014
dc.identifier.citation Boyd , Tyler D., Kumar, Ish, Wagner, Eric E., et al.. "Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)." Chemical Communications, 50, (2014) Royal Society of Chemistry: 3556-3559. http://dx.doi.org/10.1039/C4CC00056K.
dc.identifier.urihttps://hdl.handle.net/1911/76290
dc.description.abstract Reaction of BiPh3 with salicylic acid (HO-2-C6H4CO2H, H2Sal) at room temperature in wet acetonitrile or nitromethane leads to the facile formation of an oxo cluster compound with formula [Bi4(m3-O)2(HSal)8] solvated by either MeCN and MeNO2 (1×2MeCN or 1×2MeNO2). This simple procedure affords a convenient, high yield (>80%) synthesis of a single bismuth oxo cluster. Both adducts exhibit a nearly planar Bi4(m3-O)2 core. The solvent ligands are situated in the same coordination sites in both but at long Bi---N and Bi---O distances. The ease of preparation as a pure compound makes this an ideal starting material for study of bismuth oxo-salicylate chemistry.
dc.language.iso eng
dc.publisher Royal Society of Chemistry
dc.rights This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the Royal Society of Chemistry.
dc.title Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)
dc.type Journal article
dc.contributor.funder Welch Foundation
dc.citation.journalTitle Chemical Communications
dc.citation.volumeNumber 50
dc.type.dcmi Text
dc.identifier.doihttp://dx.doi.org/10.1039/C4CC00056K
dc.identifier.pmid 24562745
dc.identifier.grantID C-0976 (Welch Foundation)
dc.type.publication post-print
dc.citation.firstpage 3556
dc.citation.lastpage 3559


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