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    Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)

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    Author
    Boyd , Tyler D.; Kumar, Ish; Wagner, Eric E.; Whitmire, Kenton H.
    Date
    2014
    Abstract
    Reaction of BiPh3 with salicylic acid (HO-2-C6H4CO2H, H2Sal) at room temperature in wet acetonitrile or nitromethane leads to the facile formation of an oxo cluster compound with formula [Bi4(m3-O)2(HSal)8] solvated by either MeCN and MeNO2 (1×2MeCN or 1×2MeNO2). This simple procedure affords a convenient, high yield (>80%) synthesis of a single bismuth oxo cluster. Both adducts exhibit a nearly planar Bi4(m3-O)2 core. The solvent ligands are situated in the same coordination sites in both but at long Bi---N and Bi---O distances. The ease of preparation as a pure compound makes this an ideal starting material for study of bismuth oxo-salicylate chemistry.
    Citation
    Boyd , Tyler D., Kumar, Ish, Wagner, Eric E., et al.. "Synthesis and structural studies of the simplest bismuth(III) oxo-salicylate complex: [Bi4(m3-O)2(HO-2-C6H4CO2)8]×2 Solv (Solv = MeCN or MeNO2)." Chemical Communications, 50, (2014) Royal Society of Chemistry: 3556-3559. http://dx.doi.org/10.1039/C4CC00056K.
    Published Version
    http://dx.doi.org/10.1039/C4CC00056K
    Type
    Journal article
    Publisher
    Royal Society of Chemistry
    Citable link to this page
    https://hdl.handle.net/1911/76290
    Rights
    This is an author's peer-reviewed final manuscript, as accepted by the publisher. The published article is copyrighted by the Royal Society of Chemistry.
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    • Chemistry Publications [635]
    • Faculty Publications [4976]

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    Home | FAQ | Contact Us | Privacy Notice | Accessibility Statement
    Managed by the Digital Scholarship Services at Fondren Library, Rice University
    Physical Address: 6100 Main Street, Houston, Texas 77005
    Mailing Address: MS-44, P.O.BOX 1892, Houston, Texas 77251-1892
    Site Map