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dc.contributor.advisor Margrave, John L.
dc.creatorChang, Chin-Hsiung
dc.date.accessioned 2007-05-09T18:38:39Z
dc.date.available 2007-05-09T18:38:39Z
dc.date.issued 1967
dc.identifier.citation Chang, Chin-Hsiung. "Chemical reactions at high pressures and high temperatures." (1967) Diss., Rice University. https://hdl.handle.net/1911/14334.
dc.identifier.urihttps://hdl.handle.net/1911/14334
dc.description.abstract Two high pressure devices, the opposed anvil and the tetrahedral anvil, have been used for studying chemical reactions at high pressures and high temperatures. The effect of pressure on the thermal decomposition of potassium chlorate and mercuric oxide has been determined experimentally. New cubic mercury and cadmium metaborates were isolated and studied. Group III superoxides have been synthesized under high pressures and their properties have been investigated by x-ray, infrared, electron spin resonance and chemical methods. Three new high pressure forms of LiMO2(M = B, Al and Ga)-compounds have been synthesized and identified. It is found that y-LiB02 and y-LiA10 could be synthesized directly by reacting lithium peroxide with boric oxide and aluminum oxide respectively.
dc.format.extent 214 pp
dc.format.mimetype application/pdf
dc.language.iso eng
dc.subjectPhysical chemistry
dc.title Chemical reactions at high pressures and high temperatures
dc.identifier.digital RICE0067
dc.type.genre Thesis
dc.type.material Text
thesis.degree.department Chemistry
thesis.degree.discipline Natural Sciences
thesis.degree.grantor Rice University
thesis.degree.level Doctoral
thesis.degree.name Doctor of Philosophy
dc.format.digitalOrigin reformatted digital
dc.identifier.callno Thesis Chem. 1967 Chang


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