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dc.contributor.authorFertman, Elena L.
Fedorchenko, Alexey V.
Čižmár, Erik
Vorobiov, Serhii
Feher, Alexander
Radyush, Yury V.
Pushkarev, Anatoli V.
Olekhnovich, Nikolai M.
Stanulis, Andrius
Barron, Andrew R.
Khalyavin, Dmitry D.
Salak, Andrei N.
dc.date.accessioned 2020-11-06T02:02:48Z
dc.date.available 2020-11-06T02:02:48Z
dc.date.issued 2020
dc.identifier.citation Fertman, Elena L., Fedorchenko, Alexey V., Čižmár, Erik, et al.. "Magnetic Diagram of the High-Pressure Stabilized Multiferroic Perovskites of the BiFe1-yScyO3 Series." Crystals, 10, no. 10 (2020) MDPI: https://doi.org/10.3390/cryst10100950.
dc.identifier.urihttps://hdl.handle.net/1911/109517
dc.description.abstract Magnetic properties of the high-pressure stabilized perovskite BiFe1-yScyO3 phases (0.1 ≤ y ≤ 0.9) have been studied by means of magnetization measurements and neutron diffraction. The metastable perovskites of this series undergo irreversible polymorphic transformations upon annealing, the phenomenon referred to as conversion polymorphism. It has been found that the solid solutions with y ≥ 0.70 exhibit no long-range magnetic ordering regardless of their polymorph modification, while those with y ≤ 0.60 are all antiferromagnets. Depending on the scandium content, temperature and structural distortions, three types of the antiferromagnetic orderings, involving collinear, canted and cycloidal spin arrangements, have been revealed in the phases obtained via conversion polymorphism and the corresponding magnetic phase diagram has been suggested.
dc.language.iso eng
dc.publisher MDPI
dc.rights This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.title Magnetic Diagram of the High-Pressure Stabilized Multiferroic Perovskites of the BiFe1-yScyO3 Series
dc.type Journal article
dc.citation.journalTitle Crystals
dc.subject.keywordhigh-pressure synthesis
conversion polymorphism
oxygen octahedral tilting
G-type antiferromagnetic
weak ferromagnetism
collinear magnetic ground state
dc.citation.volumeNumber 10
dc.citation.issueNumber 10
dc.type.dcmi Text
dc.identifier.doihttps://doi.org/10.3390/cryst10100950
dc.type.publication publisher version
dc.citation.articleNumber 950


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