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    Matrix reactions of uranium fluorides as studied by infrared spectroscopy

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    Author
    Hamill, Delphia F.
    Date
    1977
    Advisor
    Margrave, John L.
    Degree
    Master of Arts
    Abstract
    The Infrared spectra of UF^4 were recorded In matrices of neon, argon, krypton, xenon, oxygen, nitrogen, nitric oxide, and carbon monoxide* The data from these spectra support a tetrahedral structure for UF^4 in the gas phase. The relative interaction of the above-mentioned matrices with UF^4. was found to increase in order from neon 4 to carbon monoxide. The deposition of UF^4 in fluorine doped argon and nitrogen matrices resulted in production of UF^5 and UF^6, the relative intensities of their respective infrared bands depending on the concentration of fluorine in the matrix. Nitrogen and carbon monoxide doped argon matrices were also studied.
    Citation
    Hamill, Delphia F.. "Matrix reactions of uranium fluorides as studied by infrared spectroscopy." (1977) Master’s Thesis, Rice University. http://hdl.handle.net/1911/104755.
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    • Rice University Electronic Theses and Dissertations [12052]

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    Managed by the Digital Scholarship Services at Fondren Library, Rice University
    Physical Address: 6100 Main Street, Houston, Texas 77005
    Mailing Address: MS-44, P.O.BOX 1892, Houston, Texas 77251-1892