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dc.contributor.advisor Hulet, Randall G.
dc.creatorJunker, Mark
dc.date.accessioned 2018-12-03T18:31:50Z
dc.date.available 2018-12-03T18:31:50Z
dc.date.issued 2008
dc.identifier.urihttps://hdl.handle.net/1911/103607
dc.description.abstract The rate of photoassociation (PA) determines how quickly molecules form from atoms illuminated by a resonant laser pulse. Knowledge of limits of this molecular formation rate provide a fundamental component on the maximum rate that a tightly bound ground state molecular Bose-Einstein condensate (BEC) could be formed using a two-photon transition. This molecular synthesis represents the beginning of a new era of ultracold quantum chemistry. The available Feshbach resonance in this system is an indispensable tool to increase the molecular formation rate due to PA in the anticipation of revealing these fundamental rate limits. While the rate saturates in a thermal gas, no evidence of saturation has yet been observed in a BEC. A loss of atoms due to a PA pulse tuned to the v " = 83 excited state molecular vibrational level provides the measurement of the PA rate. The rate varies by several orders of magnitude either by tuning the magnetic field near a Feshbach resonance or by adjusting the PA intensity. We measure the PA rate at magnetic fields between 550-900 Gauss in a BEC and a thermal gas, which is near the Feshbach resonance at 736 Gauss. The rapidly changing rate near the Feshbach resonance reflects the overlap between the ground state and the excited state wavefunctions. We present the first quantitative measurement of the PA rate near a Feshbach resonance. We measure the magnetic field dependence of the molecular resonance position near the Feshbach resonance. We introduce the first observation of a positive energy shift associated with photoassociation. The measured energy shift asymptotically diverges as it approaches the Feshbach resonance and agrees qualitatively with described theory at all magnetic fields. We observe intensity dependent saturation in the PA rate in a thermal gas and the measurements qualitatively agree with a unitarity limited rate. The first conclusive evidence for a suppression of the PA rate occurs for intensities above the saturation intensity. We report the first observed saturation of the PA rate in a BEC. Three separate theories present possible mechanisms for the observed saturation.
dc.format.extent 198 pp
dc.language.iso eng
dc.subjectMolecular physics
Condensed matter physics
Pure sciences
Bose-Einstein condensate
Feshbach resonance
.Lithium-7
Photoassociation
dc.title Single photon photoassociation in a lithium-7 BEC near a Feshbach resonance
dc.identifier.digital 304510434
dc.type.genre Thesis
dc.type.material Text
thesis.degree.department Physics
thesis.degree.discipline Natural Sciences
thesis.degree.grantor Rice University
thesis.degree.level Doctoral
thesis.degree.name Doctor of Philosophy
dc.identifier.callno THESIS PHYS. 2008 JUNKER
dc.identifier.citation Junker, Mark. "Single photon photoassociation in a lithium-7 BEC near a Feshbach resonance." (2008) Diss., Rice University. https://hdl.handle.net/1911/103607.


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